Structural revision of some recently published iridoid glucosides Soren R. Jensen, Ihsan Calis, Charlotte H.Gotfredsen, Inger Sotofte.
Materyal türü:
MakaleDil: İngilizce Yayın ayrıntıları:2007. Amer Chemical Soc, Washington :ISSN: - 0163-3864
- QD31.2
| Materyal türü | Geçerli Kütüphane | Yer numarası | Durum | Barkod | |
|---|---|---|---|---|---|
| Online Electronic Document | NEU Grand Library Online electronic | QD31.2 .S77 2007 (Rafa gözat(Aşağıda açılır)) | Ödünç verilmez | EOL-1268 |
The structures of six different iridoid glucosides have been revised. Three compounds isolated from Eremostachys glabra and designated 6,9-epi-8-O-acetylshanziside (1), 5,9-epi-penstemoside (2), and 5,9-epi-7,8-didehydropenstemoside (3) have been shown to be identical to the known iridoids barlerin (4, 8-O-acetylshanziside), penstemoside (5), and 7,8-didehydropenstemoside (6), respectively. Another compound named harpagoside-B, isolated from Scrophularia deserti and proposed to be 9-epi-6-O-methylharpagoside (11), was demonstrated from the spectroscopic data given to be the known harpagoside (10b). Finally, two alleged iridoid galactosides from Buddleja crispa named buddlejosides A and B (12a and 12b) have been shown to be the corresponding glucosides; the former is identical to agnuside (13a), while the latter is 3,4-dihydroxybenzoylaucubin (13b), an iridoid glucoside not previously published. This clearly showed that care should be taken with the interpretation of NOEs involving bridgehead protons in iridoid structures because they can be capricious and lead to erroneous structural assignments.
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