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A New Sulfated α-Ionone Glycoside from Sonchus erzincanicus Ufuk Ozgen, Handan Sevindik, Cavit Kazaz, Demet Yigit, Ali Kandemir, Hasan Secen, Ihsan Calis

Yazar: Materyal türü: MakaleMakaleDil: İngilizce Yayın ayrıntıları:2010.ISSN:
  • 1420-3049
Konu(lar): LOC sınıflandırması:
  • QV700
Çevrimiçi kaynaklar: İçindekiler: Molecules 2010, 15(4), 2593-2599Özet: Sonchus erzincanicus (Asteraceae) is an endemic species in Turkey, where six Sonchus species grow. In this study, a phytochemical study was performed on the aerial parts of the plant. The study describes the isolation and structure elucidation of five flavonoids and two α-ionone glycosides from S. erzincanicus. The compounds were isolated using several and repeated chromatographic techniques from ethyl acetate and aqueous phases that were partitioned from a methanol extract obtained from the plant. 5,7,3',4'-Tetrahydroxy-3-methoxyflavone (1) and quercetin 3-O-β-D-glucoside (2) were isolated from the ethyl acetate phase, while corchoionoside C 6’-O-sulfate (3), corchoionoside C (4), luteolin 7-O-glucuronide (5) and luteolin 7-O-β-Dglucoside (6), apigenin 7-O-glucuronide (7) were isolated from the aqueous phase. Corchoionoside C 6’-O-sulfate (3), isolated for the first time from a natural source, was a new compound. The structures of the compounds were elucidated by means of 1H-NMR, 13C-NMR, 2D-NMR (COSY, HMQC, HMBC) and ESI-MS.
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Online Electronic Document NEU Grand Library Online electronic QV700 .N49 2010 (Rafa gözat(Aşağıda açılır)) Ödünç verilmez EOL-736

Sonchus erzincanicus (Asteraceae) is an endemic species in Turkey, where six Sonchus
species grow. In this study, a phytochemical study was performed on the aerial parts of the plant.
The study describes the isolation and structure elucidation of five flavonoids and two α-ionone
glycosides from S. erzincanicus. The compounds were isolated using several and repeated
chromatographic techniques from ethyl acetate and aqueous phases that were partitioned from a
methanol extract obtained from the plant. 5,7,3',4'-Tetrahydroxy-3-methoxyflavone (1) and
quercetin 3-O-β-D-glucoside (2) were isolated from the ethyl acetate phase, while corchoionoside
C 6’-O-sulfate (3), corchoionoside C (4), luteolin 7-O-glucuronide (5) and luteolin 7-O-β-Dglucoside
(6), apigenin 7-O-glucuronide (7) were isolated from the aqueous phase. Corchoionoside
C 6’-O-sulfate (3), isolated for the first time from a natural source, was a new compound. The
structures of the compounds were elucidated by means of 1H-NMR, 13C-NMR, 2D-NMR (COSY,
HMQC, HMBC) and ESI-MS.

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